Hydrofluoric Acid
Hydrofluoric Acid is a colourless gas or a fuming liquid and is a poison.
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HF is the precursor for almost all fluorine compounds such as fluorides andÌýorganofluorineÌýcompounds.Ìý​
It can dissolve most oxides and silicates and is often used as a cleaning agent for stainless and carbonÌýsteels.
Recommended control measures​
This is a controlled chemicalÌý(Poison (°×С½ãÂÛ̳ ref PA033)) – see information on standards for all controlledÌýchemicals
Always have a designated HF treatment and spill kit available​
Minimise the likelihood of exposure​
- Only work within a dedicated fume cupboard that has warning signs
- Avoid heating and other activates that would produce a gas
- If HF gas is produced, or hydrofluoric acid (a solution of HF in water), do not store in glass as it reacts withÌýthe container
- Always use the most appropriate gloves for the work being done. Chemical resistance gloves do provideÌýprotection againstÌýHFÌýbut this depends on the concentration of HF e.g. level 6 gloves (highest for chemicalÌýresistance) will provide full protection (> 480 minutes for 10% solution but only 21 minutes for a 73%Ìýsolution
First aid​
- Wash exposed skin forÌýat least 20 minutes. Rinse exposed eyes for at leastÌý20Ìý³¾¾±²Ô³Ü³Ù±ð²õ
- Apply calcium gluconate gel to the area. Wear gloves while doing this to prevent secondary exposure. TheÌýgel will turn white when it reacts with the acid
- As symptoms may not occur for several hours, treatment must be given to all suspected areas ofÌýexposure​
- Take to the hospital as soon as possible​
- If exposed to a gas, you can treat with oxygen​
- If ingested do not induce vomiting​
Health surveillanceÌý​
Not required.
Chemical safety library
> Read more about control measures for chemicals in our chemical safety libraryÌý
Last updated: Tuesday, June 23, 2020